Anglo-Saxon mordants

This is the next post about my Anglo-Saxon-style experiments.

Today’s natural dyers tend to use mainly aluminium mordants and sometimes iron and copper, which may also be used after dyeing as colour modifiers. Chrome, which was not introduced as a mordant until the 19th century, has been popular among some dyers but is avoided by many nowadays because of its toxicity. Similarly tin, which was first used as a mordant in the 17th century (mainly with cochineal to produce bright reds) is now less frequently used, partly because of environmental considerations and partly because it can make fibres brittle. Copper was used by early dyers in the Mediterranean world and also in India in the classical period AD300 – 700 but, of the metallic mordants mentioned above, only alum and iron seem to have been used by the Anglo-Saxons. It is also possible that pots made of metals, such as iron or bronze, may have been used as dyepots and this may have had an effect on the colours. However, the only evidence of dyestuffs staining pots in the early Anglo-Saxon period occurred in pots made of clay and dyeing may have frequently been carried out in clay pots, which would probably not have had a significant effect on the colours produced.

Many of the dyes used by Anglo-Saxon dyers will fix adequately without a mordant and I think it is likely that many fibres would have been dyed in this way. Some textile fragments from the period show evidence of an alum mordant and mineral alum from the Mediterranean was probably used during the later Anglo-Saxon period. However, there is some doubt as to whether this mineral alum would have been available earlier in the period, so alternative mordants may have been used, such as aluminium extracted from clubmosses. Plants rich in tannins, such as oak galls and blackberry leaves and shoots, may also have been used as mordants.

In my experiments I tested most dyes in the following ways:

  • Without a mordant
  • With a 10% mineral alum mordant
  • With alum extracted from clubmoss
  • With a tannin mordant (from oak galls or bramble/blackberry leaves and twigs)
  • With an iron mordant / use of an iron pot

As clubmosses are rare in Britain, I would not advocate their use, except in very small quantities for experimental purposes. For my tests I used the following recipe for clubmoss as a mordant:

Use 200% clubmoss (Lycopodium spp), chop it up and put it into a pot filled with water, then heat to 40C. Hold at this temperature for 3 days. On the fourth day boil it up briefly and then strain off the liquid. Add the fibres to be mordanted, heat slowly to 40C and then allow to cool  Repeat this process daily for 3 days. Then remove the fibres and squeeze the excess liquid back into the solution, which can be re-used once. In order to be sure that aluminium had been extracted and then absorbed by the fibres, I used fibres mordanted with 10% mineral alum and unmordanted fibres as “controls” in the dyebath. The results were particularly clear with madder dye – the unmordanted fibres dyed to a coral shade but both the alum-mordanted and the clubmoss mordanted fibres dyed to an almost identical red shade.

In these tests I used 100% bramble/blackberry leaves and twigs as a tannin mordant. I simmered them for about one hour to extract the tannin, then strained off the liquid, added the fibres and simmered them for about 45 minutes, then left them in the liquid to cool overnight. (25% oak galls can be used instead of bramble leaves and twigs.)

I also experimented with the use of iron and wood-ash-water, which is alkaline, as colour modifiers after dyeing. It is also possible that stale urine may have been added to dyebaths and this would have increased alkalinity.

To make iron water, put some pieces of scrap iron or rusty nails in a large container with a well-fitting lid and fill it up with a solution of two parts water to one part clear vinegar. Leave the iron to steep in this solution for a week or two, until the solution is orange in colour. When you use the iron water, strain it through a fine-meshed sieve or a piece of muslin.

To make wood-ash water, put the ashes from a wood fire into a large glass or plastic container with a well-fitting lid. Fill up with water and leave the ashes to steep for a week or two, until the liquid is yellow in colour and feels slick or slimy to the touch. When you use the solution, pour or siphon it off without disturbing the ash sediment. Wood-ash water can be used as an alkaline modifier and as the source of alkali in woad vats. It can also be added to dyer’s broom and weld dyebaths to increase the depth of colour.

My experiments are intended to demonstrate some of the possible methods used by Anglo-Saxon dyers and to give an idea of the colour range they might have achieved. Although we don’t know exactly how early dyers worked, there is enough evidence to indicate that they would have been able to achieve a wide range of bright, rich colours from the relatively small number of dyes they used.

I will write about individual dyes in later posts.

6 Responses to “Anglo-Saxon mordants”

  1. arlee says:

    Thanks for sharing these insights. My Greyman built me a little "eco-cooker" (airtight woodstove) and my outside experiments will be as close to "natural" as possible with it and these tips.

  2. Thanks for sharing your experiments.  I wonder if there might be iron in the clay pots as well?  Clay in our area is usually rich in metal salts — especially iron.  I have some modern pottery dishes that I can't microwave because there is iron in the clay used by the potter.

    And some pottery glazes get their colours from metal salts as well.  I'm not sure if these would affect a dye bath after firing, but if iron leaches from a cauldron into a dye bath, perhaps the pottery glaze would also leach.
    Just a thought.
    Chris

    • jennydean.co.uk says:

      Thanks for these useful comments., Chris. They certainly give me some food for further thought.

  3. india flint says:

    Jenny, i'd think twice about using plastic containers for brewing mordants…they release phthalates into their contents and even plain water can feel quite slimy after a couple of weeks in contact with a plastic surface; so a heavily alkaline solution may [after similar storage] also contain a higher than usual percentage of unexpected additives. Glass is by far the better option, being non-reactive. Interesting to read about your experiments, thank you

    • jennydean.co.uk says:

      Thanks for this useful comment, India. I do usually use glass for storage of mordants etc but sometimes I run out of glass containers, especially as I gave away my stock of large glass jars when we moved. The plastic bottles or containers I occasionally use are those guaranteed as safe for food & drink storage, but perhaps I’ve been too naive in believing all the advertising info?! I am now asking family & friends to save glass jars for me.

  4. Shirley Deming says:

    Thank you for your post! I've often wondered how our ancestors got their mordants without chemists. Also, thank you for posting the proportions that you used. (I've been using far too little, and getting poor results.) I'm going to return to your blog often to get new information and comparing results. This will greatly enhance my living-history studies.